Determining the standard reduction potentials of

As you move down on your reduction potential, you have an increasing tendency to be oxidized. For H2, you can quantitatively deduce whether the given metal will dissolve in aqueous solution. Standard reduction potentials can be useful in determining the directionality of a reaction.

We know that zinc is being oxidized, right?

calculate the standard potential for the following galvanic cell:

It is capable of reducing any substance above on the table. It is the tendency for a species to be oxidized at standard conditions. All of these half-reactions are written as reduction half-reactions.

cell potential

For this reason, the potential difference contributed by the left half-cell has the opposite sign to its conventional reduction half-cell potential. The SHE is rather dangerous and rarely used in the laboratory. We need to find the standard oxidation potential for this half-reaction.

Standard reduction potential table pdf

This means the reaction is spontaneous and Zn will dissolve in HCl. As you move up on your standard reduction potential, increased strength as an oxidizing agent. Figure 1 - Standard Hydrogen Electrode Universally, hydrogen has been recognized as having reduction and oxidation potentials of zero. For H2, you can quantitatively deduce whether the given metal will dissolve in aqueous solution. These are simply the negative of standard reduction potentials, so it is not a difficult conversion in practice. Hydrogen gas at 1 atm is bubbled through 1 M HCl solution. In order to express them in a uniform way, we follow the rule that half-cell potentials are always defined for the reduction direction. Let's go ahead and write that. In situations where an electrochemical series is not sufficient to absolutely determine the direction of a redox reaction, the standard electrode potential, Eo, can be used. All of our other half-reactions are compared to this one. For more information view Cell Potentials. Its main significance is that it established the zero for standard reduction potentials. If you immerse a piece of metallic zinc in a solution of copper sulfate, the surface of the zinc quickly becomes covered with a coating of finely divided copper.

The electrode chosen as the zero is shown in Figure 1 and is called the standard hydrogen electrode SHE.

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Calculating Standard Cell Potentials ( Read )